Hyperpolarized NMR: d-DNP, PHIP, and SABRE

Kirill Viktorovich Kovtunov (1) , Ekaterina Pokochueva (1) , Oleg Salnikov (1) , Samuel Cousin (2) , Dennis Kurzbach (3) , Basile Vuichoud (2) , Sami Jannin (2) , Eduard Chekmenev (4) , Boyd Goodson (5) , Danila Barskiy (6) , Igor Koptyug (1)

1 Laboratory of Magnetic Resonance Microimaging
2 ISA - Hyperpolarized Magnetic Resonance
3 LBM-E3 - Structure et Dynamique des Biomolécules
4 Department of chemistry
5 Department of Chemistry and Biochemistry [Carbondale]
6 PINESLAB

Dynamic nuclear polarization (DNP) can boost sensitivity in nuclear magnetic resonance (NMR) experiments by several orders of magnitude. This review illustrates how the coupling of DNP with both liquid-and solid-state NMR spectroscopy has the potential to considerably extend the range of applications of NMR in analytical chemistry.

Domaines: Chimie analytique

Kirill Viktorovich Kovtunov, Ekaterina Pokochueva, Oleg Salnikov, Samuel Cousin, Dennis Kurzbach, et al.. Hyperpolarized NMR: d-DNP, PHIP, and SABRE. Chemistry - An Asian Journal, 2018, Accepted manuscript online. ⟨10.1002/asia.201800551⟩. ⟨hal-01833003⟩